2020-2019

2020

135) 2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943
P. K. Mykhailiuk*
Chem. Rev. 2020, 120, 22, 12718-12755

2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943

134) Saturated Bioisosteres of ortho‐Substituted Benzenes
A. Denisenko, P. Garbuz, S. V. Shishkina, N. M. Voloshchuk, P. K. Mykhailiuk*
Angew. Chem. Int. Ed. 2020, 59, 46, 20515-20521
Saturated Bioisosteres of ortho‐Substituted Benzenes

133) Water‐soluble non‐classical benzene mimics
V. Levterov, Y. Panasyuk, V. Pivnytska, P. K. Mykhailiuk*
Angew. Chem. Int. Ed. 2020, 59, 18, 7161-7167
Water‐soluble non‐classical benzene mimics

132) Deoxofluorination of (Hetero)aromatic Acids
S. Trofymchuk, M. Ya. Bugera, A. A. Klipkov, B. Razhyk, S. Semenov, K. Tarasenko, V. S. Starova, O. A. Zaporozhets, O. Yu. Tananaiko, A. N. Alekseenko, Y. Pustovit, O. Kiriakov, I. I. Gerus, A. A. Tolmachev, P. K. Mykhailiuk*
J. Org. Chem. 2020, 85, 5, 3110-3124
Deoxofluorination of (Hetero)aromatic Acids

131) Diazoacetonitrile (N2CHCN): a long forgotten but valuable reagent for organic synthesis
P. K. Mykhailiuk,* R. M. Koenigs*
Сhem. Eur. J. 2020, 26, 1, 89-101
Diazoacetonitrile (N2CHCN): a long forgotten but valuable reagent for organic synthesis

2019

130) Convenient Access to Conformationally Rigid Sultams
D. Dibchak, V. Scherbacova, A. V. Denisenko, P. K. Mykhailiuk*
Org. Lett. 2019, 21, 22, 8909-8914
Convenient Access to Conformationally Rigid Sultams

129) Difluoro-Substituted bicyclo[1.1.1]pentanes as Novel Motifs for Medicinal Chemistry: Design, Synthesis and Characterization
R. M. Bychek, V. Hutskalova, J. P. Bas, O. A. Zaporozhets, S. Zozulia, V. V. Levterov,
P. K. Mykhailiuk*
J. Org. Chem. 2019, 84, 23, 15106-15117
Difluoro-Substituted bicyclo[1.1.1]pentanes as Novel Motifs for Medicinal Chemistry: Design, Synthesis and Characterization

128) Deoxofluorination of Aliphatic Carboxylic Acids: A Route to Trifluoromethyl-Substituted Derivatives
M. Bugera. S. Trofymchuk, K. Tarasenko, O. Zaporozhets, Y. Pustovit, P. K. Mykhailiuk*
J. Org. Chem. 2019, 84, 26, 16105-16115
Deoxofluorination of Aliphatic Carboxylic Acids: A Route to Trifluoromethyl-Substituted Derivatives

127) Hindered dialkyl ether synthesis via electrogenerated carbocations
J. Xiang, M. Shang, Y. Kawamata, H. Lundberg, S. Reisberg, M. Chen, P. Mykhailiuk, G. Beutner, M. Collins, A. Davies, M. Del Bel, G. Gallego, J. Spangler, J. T. Starr, S. Yang, D. Blackmond, P. Baran
Nature 2019, 573, 398-402
Hindered dialkyl ether synthesis via electrogenerated carbocations

126) A radical approach to anionic chemistry: synthesis of ketones, alcohols, and amines
S. Ni, N. M. Padial, C. Kingston, J. C. Vantourout, D. C. Schmitt, J. T. Edwards, M. M. Kruszyk, R. R. Merchant, P. K. Mykhailiuk, B. B. Sanchez, S. Yang, M. A. Perry, G. M. Gallego, J. J. Mousseau, M. R. Collins, R. J. Cherney, P. S. Lebed, J. S. Chen, T. Qin, P. S. Baran
J. Am. Chem. Soc. 2019, 141, 6726-6739
A radical approach to anionic chemistry: synthesis of ketones, alcohols, and amines

125) Electrochemical C(sp3)–H Fluorination
Y. Takahira, M. Chen, Y. Kawamata, P. Mykhailiuk, H. Nakamura, B. K. Peters, S. H. Reisberg, C. Li, L. Chen, T. Hoshikawa, T. Shibuguchi, P. S. Baran
Synlett 2019, 30, 1178-1182
Electrochemical C(sp3)–H Fluorination

124) Carbonyl complexes of copper(I) stabilized bybridging fluorinated pyrazolates and halide ions
D. Parasar, N. B. Jayaratna, A. Muñoz-Castro, A. E. Conway, P. K. Mykhailiuk, H. V. R. Dias
Dalton. Trans. 2019, 48, 6358-6371

123) Quaternary Centers via Ni-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and Aryl Zinc Reagents
T. -G. Chen, H. Zhang, P. K. Mykhailiuk, R. R. Merchant, C. A. Smith, T. Qin, P. S. Baran
Angew. Chem. Int. Ed. 2019, 59, 2454-2458
Quaternary Centers via Ni-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and Aryl Zinc Reagents

122) CH-Activation of Proline analogues
V. Hutskalova, P. K. Mykhailiuk*
Org. Biomol. Chem. 2019, 17, 4342-4349
CH-Activation of Proline analogues

121) Saturated Bioisosteres of Benzene: Where to go Next?
P. K. Mykhailiuk*
Org. Biomol. Chem. 2019, 17, 2839-2849
Saturated Bioisosteres of Benzene: Where to go Next?

120) Difluorodiazoethane (CF2HCHN2): a new reagent for the introduction of the difluoromethyl group
P. K. Mykhailiuk,* R. M. Koenigs*
Chem. Eur. J. 2019, 25, 6053-6063
Difluorodiazoethane (CF2HCHN2): a new reagent for the introduction of the difluoromethyl group

119) Practical synthesis of 2,2-disubstituted spirocyclic pyrrolidines by Dieckmann condensation
K. Fominova, T. Diachuk, I. Sadkova, P. K. Mykhailiuk*
Eur. J. Org. Chem. 2019, 22, 3553-3559
Practical synthesis of 2,2-disubstituted spirocyclic pyrrolidines by Dieckmann condensation

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