2020
135) 2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943
P. K. Mykhailiuk*
Chem. Rev. 2020, 120, 22, 12718-12755

134) Saturated Bioisosteres of ortho‐Substituted Benzenes
A. Denisenko, P. Garbuz, S. V. Shishkina, N. M. Voloshchuk, P. K. Mykhailiuk*
Angew. Chem. Int. Ed. 2020, 59, 46, 20515-20521

133) Water‐soluble non‐classical benzene mimics
V. Levterov, Y. Panasyuk, V. Pivnytska, P. K. Mykhailiuk*
Angew. Chem. Int. Ed. 2020, 59, 18, 7161-7167

132) Deoxofluorination of (Hetero)aromatic Acids
S. Trofymchuk, M. Ya. Bugera, A. A. Klipkov, B. Razhyk, S. Semenov, K. Tarasenko, V. S. Starova, O. A. Zaporozhets, O. Yu. Tananaiko, A. N. Alekseenko, Y. Pustovit, O. Kiriakov, I. I. Gerus, A. A. Tolmachev, P. K. Mykhailiuk*
J. Org. Chem. 2020, 85, 5, 3110-3124

131) Diazoacetonitrile (N2CHCN): a long forgotten but valuable reagent for organic synthesis
P. K. Mykhailiuk,* R. M. Koenigs*
Сhem. Eur. J. 2020, 26, 1, 89-101

2019
130) Convenient Access to Conformationally Rigid Sultams
D. Dibchak, V. Scherbacova, A. V. Denisenko, P. K. Mykhailiuk*
Org. Lett. 2019, 21, 22, 8909-8914

129) Difluoro-Substituted bicyclo[1.1.1]pentanes as Novel Motifs for Medicinal Chemistry: Design, Synthesis and Characterization
R. M. Bychek, V. Hutskalova, J. P. Bas, O. A. Zaporozhets, S. Zozulia, V. V. Levterov,
P. K. Mykhailiuk*
J. Org. Chem. 2019, 84, 23, 15106-15117
![Difluoro-Substituted bicyclo[1.1.1]pentanes as Novel Motifs for Medicinal Chemistry: Design, Synthesis and Characterization](http://mykhailiukchem.org/wp-content/uploads/2019/09/129_comp.png)
128) Deoxofluorination of Aliphatic Carboxylic Acids: A Route to Trifluoromethyl-Substituted Derivatives
M. Bugera. S. Trofymchuk, K. Tarasenko, O. Zaporozhets, Y. Pustovit, P. K. Mykhailiuk*
J. Org. Chem. 2019, 84, 26, 16105-16115

127) Hindered dialkyl ether synthesis via electrogenerated carbocations
J. Xiang, M. Shang, Y. Kawamata, H. Lundberg, S. Reisberg, M. Chen, P. Mykhailiuk, G. Beutner, M. Collins, A. Davies, M. Del Bel, G. Gallego, J. Spangler, J. T. Starr, S. Yang, D. Blackmond, P. Baran
Nature 2019, 573, 398-402

126) A radical approach to anionic chemistry: synthesis of ketones, alcohols, and amines
S. Ni, N. M. Padial, C. Kingston, J. C. Vantourout, D. C. Schmitt, J. T. Edwards, M. M. Kruszyk, R. R. Merchant, P. K. Mykhailiuk, B. B. Sanchez, S. Yang, M. A. Perry, G. M. Gallego, J. J. Mousseau, M. R. Collins, R. J. Cherney, P. S. Lebed, J. S. Chen, T. Qin, P. S. Baran
J. Am. Chem. Soc. 2019, 141, 6726-6739

125) Electrochemical C(sp3)–H Fluorination
Y. Takahira, M. Chen, Y. Kawamata, P. Mykhailiuk, H. Nakamura, B. K. Peters, S. H. Reisberg, C. Li, L. Chen, T. Hoshikawa, T. Shibuguchi, P. S. Baran
Synlett 2019, 30, 1178-1182

124) Carbonyl complexes of copper(I) stabilized bybridging fluorinated pyrazolates and halide ions
D. Parasar, N. B. Jayaratna, A. Muñoz-Castro, A. E. Conway, P. K. Mykhailiuk, H. V. R. Dias
Dalton. Trans. 2019, 48, 6358-6371

123) Quaternary Centers via Ni-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and Aryl Zinc Reagents
T. -G. Chen, H. Zhang, P. K. Mykhailiuk, R. R. Merchant, C. A. Smith, T. Qin, P. S. Baran
Angew. Chem. Int. Ed. 2019, 59, 2454-2458

122) CH-Activation of Proline analogues
V. Hutskalova, P. K. Mykhailiuk*
Org. Biomol. Chem. 2019, 17, 4342-4349

121) Saturated Bioisosteres of Benzene: Where to go Next?
P. K. Mykhailiuk*
Org. Biomol. Chem. 2019, 17, 2839-2849

120) Difluorodiazoethane (CF2HCHN2): a new reagent for the introduction of the difluoromethyl group
P. K. Mykhailiuk,* R. M. Koenigs*
Chem. Eur. J. 2019, 25, 6053-6063

119) Practical synthesis of 2,2-disubstituted spirocyclic pyrrolidines by Dieckmann condensation
K. Fominova, T. Diachuk, I. Sadkova, P. K. Mykhailiuk*
Eur. J. Org. Chem. 2019, 22, 3553-3559










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